Material safety data sheet

MATERIAL SAFETY DATA SHEET
SECTION 1 -IDENTIFICATION

Product Name

Recommended Use
Fly Spray / Insecticide

Supplier TASMAN CHEMICALS PTY LTD
ACN : 005 072 659
Street Address 1-7 Bell Grove, Braeside ,
Victoria 3195 AUSTRALIA
Telephone Number
Facsimilie

Emergency Telephone Number 1 800 334 556

SECTION 2 - HAZARDS INDENTIFICATION
Hazardous according to criteria of Safe Work Australia.

Hazard Category :
Harmful by inhalation, in contact with skin and if swallowed Irritating to respiratory system and skin May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long term adverse effects in the aquatic Harmful: may cause lung damage if swallowed Repeated exposure may cause skin dryness and cracking Keep away from food, drink and animal feeding stuffs. Wear suitable protective clothing, gloves and eye/face protection This material and its container must be disposed of as hazardous waste
Execute is not classified as a Dangerous Good according to the Australian Code for the Transport of Dangerous
Goods by Road and Rail.

SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS

Ingredient
CAS Number
Proportion (%m/m)

VH>60% H>30-60% M=10-30% L=<10%
Issue No 3
SECTION 4 - FIRST AID MEASURES

First Aid
Swallowed:
If swallowed DO NOT induce vomiting. Wash out mouth with water. Where vomiting occurs naturally have head below hip level in order to reduce risk of aspiration Seek immediate medical assistance or contact the Poisons Information Centre immediately. If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised by the Poisons Information Centre or a doctor, or for at least 15 minutes If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Remove victim from source of contamination or move victim to fresh air. Allow patient to assume most comfortable position. Seek medical attention if effects persist.
Advice to Doctor
Treat symptomatically.
SECTION 5 - FIRE FIGHTING MEASURES

Fire/Explosion Hazard

This product should be stored and used in a well ventilated area away from naked flames, sparks and
other sources of ignition. Hoses should be electrically continuous and containers bonded to avoid static
charge build-up. Keep the container tightly closed
Extinguishing Media
Dry chemical, foam or carbon dioxide. Water spray may be used to keep fire expose containers cool
Special Fire Fighting Procedures
In the event of a fire, water full protective clothing and NIOSH approved self-contained breathing
apparatus with full face operated in the pressure demand or other positive pressure mode
SECTION 6 - ACCIDENTALRELEASE MEASURES

Spills
Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective
equipment. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain
and recover liquid when possible. Use non-sparking tools and equipment. Collect liquid in an
appropriate container or absorb with an inert material (eg vermiculite, dry sand, or earth), and place in a
chemical waste container. Do not use combustible materials, such as sawdust. Place used absorbent in
suitable sealed containers, follow state or local authority regulations and guidelines for the disposal of
the waste. Clean area with detergent and water - do not allow product to enter drains sewers or
watercourses - inform the local authorities if this occurs.
SECTION 7 - HANDLING AND STORAGE

Handling : Avoid skin and eye contact
Storage : Under normal weather conditions store in a well-ventilated area.

Keep containers closed at all times when not in use. Check regularly for leaks. SECTION 8 - EXPOSURE CONTROLS / PERSONALPROTECTION

Occupational Exposure Limits : Occupational Exposure Limits : Threshold Limit Values
Time Weighted Average ( TWA ) = 1200 mg/m3 (Aliphatic Hydrocarbon )
Exposure Standards (TWA) is the time-Weighted average airborne concentration over an eight-hour working day, for
a five day working week over an entire working life. According to current knowledge this concentration should neither
impair the health or, cause undue discomfort to, nearly all workers.
Engineering Control Measures : Natural ventilation should be adequate under normal use conditions,
Keep containers closed when not in use.

Personal Protective Equipment :
Eye:
Always wash hands before eating, drinking, smoking or using the toilet. Wash contaminated clothing and other protective equipment before storage and reuse. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
SECTION 10 - STABILITY AND REACTIVITY

Stability
Incompatible with strong oxidising agents
Reactivity
SECTION 11 - TOXOLOGICAL INFORMATION

Health Effects
No adverse health effects expected if the material is handled in accordance with the Material Safety Data
Sheet. Symptoms that may arise if the material is mishandled are :
Acute Effects

Swallowing:
Ingestion causes burning sensation in mouth and stomach, nausea, vomiting and salivation. Minute amounts aspirated into the lungs can produce a severe hemorrhagic pneumonitis with severe pulmonary injury. LD50 (Permethrin 25:75) = 400 mg/kg (Rat) Will cause eye irritation. Splashes cause severe irritation, possible corneal burns and eye damage. Skin contact results in loss of natural oils and often results in a characteristic dermatitis. May be absorbed through the skin. Inhalation of vapours may be irritating to the nose and throat. Inhalation of high concentrations may result in nausea, vomiting, headache, ringing in the ears, and severe breathing difficulties which may be delayed in onset. LC50 (Permethrin 25:75) = 25 mg/l/ 10 h (Rat) Chronic Effects
Chronic inhalation can cause headache, loss of appetite, nervousness and pale skin. Repeated or
prolonged skin contact may cause a skin rash. Repeated exposure of the eyes to high concentrations of
vapor may cause reversible eye damage.
SECTION 12 - ECOLOGICAL INFORMATION
Do not contaminate waterways. Minor spills and residue may be hosed down with excess water to trade waste treatment plant. Major spills should be contained, and placed in sealed plastic or epoxy-lined drums for disposal SECTION 13 - DISPOSAL CONSIDERATIONS
Dispose of waste according to federal, EPA and state regulations. If possible contain spill. Place inert absorbent material onto spillage. Use clean non-sparking tools to collect the material and place into a suitable labelled container. Do not dilute BUT contain. If large quantities of this material enters the waterways contact the Environmental Protection Authority or you local Waste Management Authority SECTION 14 - TRANSPORT INFORMATION
Classified as a Dangerous Good by the Criteria of the Australian Dangerous Good Code Proper Shipping Name : SECTION 15 - REGULATORY INFORMATION

Classification
Based upon information, classified as hazardous according to criteria of Safe Work Australia
Poisons Schedule
SECTION 16 - OTHER INFORMATION

Contact Points
Organisation
Location
Telephone
MSDS are updated frequently. Please ensure that you have a current copy. This MSDS summarises our best knowledge of the health and safety hazard information of the product; how to safely handle and use the product in the workplace. If clarification or further information is needed to ensure that an appropriate risk assessment can be made, the user should contact Tasman Chemicals Pty Ltd. Our responsibility for products sold are subject to our standard terms and conditions, a copy of which appears on all invoices. It is also available on request. Where health or safety data given discloses a risk to the user or environment, it is the responsibility of the Purchaser to pass on that information to employees or those who may be using the product, ensuring that adequate safety procedures are used including good industrial hygiene.

Source: http://www.tasmanchemicals.com.au/pdf/Execute.pdf