Msds cell_a123 systems, inc.

Product Name: High Power Lithium Ion Cell, Phosphate-Based MATERIAL SAFETY DATA SHEET
Protective
NFPA Rating
Transportation
Clothing
Classification
(Canada)
Not required with
Not Dangerous
normal use

Section 1:
Product and Company Information

Product Name:
High Power Lithium Ion Cell, Phosphate-Based
Product Code:
APR18650M1, Model No. FS300030 AVR18650M1, Model No. FS300031 AHR32113-Ultra-A, Model No. FS300045 AHR32157-M1-A, Model No. FS300055 Product Use:

Chemical Family:


Synonyms:

High Power Lithium Ion Battery, Phosphate-Based Manufacturer:
Phone Number:

24-hour Emergency:

Section 2:
Composition and Ingredient Information
As a solid, manufactured article, exposure to hazardous ingredients is not expected with normal use. USA: This battery is an article pursuant to 29 CFR 1910.1200 and, as such, is not subject to the OSHA Hazard Communication Standard requirement. The information contained in this Material Safety Data Sheet contains valuable information critical to the safe handling and proper use of the product. This MSDS should be retained and available for employees and other users of this product. Canada: This is not a controlled product under WHMIS. This product meets the definition of a “manufactured article” and is not subject to the regulations of the Hazardous Products Act. Product Name: High Power Lithium Ion Cell, Phosphate-Based MATERIAL SAFETY DATA SHEET
Section 3:
Hazards Identification

Preparation Hazards and
Not dangerous with normal use. The battery should not be opened or burned. Exposure to the Classification:
ingredients contained within or their combustion products could be harmful. European Communities (EC): This product is not classified as dangerous according to Directive 1999/45/EC and its amendments. This product contains dangerous ingredients however, there is no expected release during use of the product and there is a barrier preventing exposure of the user and the environment. Appearance, Color and Odor:

Primary Route(s) of Exposure:
These chemicals are contained in a sealed enclosure. Risk of exposure occurs only if the cell is mechanically, thermally or electrically abused to the point of compromising the enclosure. If this occurs, exposure to the electrolyte solution contained within can occur by Inhalation, Ingestion, Eye contact and Skin contact. Potential Health Effects:
ACUTE (short term): see Section 8 for exposure controls

In the event that this battery has been ruptured, the electrolyte solution contained within the
battery would be corrosive and can cause burns.
Inhalation: Inhalation of materials from a sealed battery is not an expected route of exposure. Vapors or
mists from a ruptured battery may cause respiratory irritation. Ingestion: Swallowing of materials from a sealed battery is not an expected route of exposure. Swallowing
the contents of an open battery can cause serious chemical burns of mouth, esophagus, and Skin: Contact between the battery and skin will not cause any harm. Skin contact with contents of an
open battery can cause severe irritation or burns to the skin. Eye: Contact between the battery and the eye will not cause any harm. Eye contact with contents of
an open battery can cause severe irritation or burns to the eye. CHRONIC (long term): see Section 11 for additional toxicological data
Not applicable
Medical Conditions
Aggravated by Exposure:
Product Name: High Power Lithium Ion Cell, Phosphate-Based MATERIAL SAFETY DATA SHEET
Section 4:
First Aid Measures

Inhalation:
If contents of an opened battery are inhaled, remove source of contamination or move victim to Eye Contact:
If eye contact with contents of an open battery occurs, immediately flush the contaminated eye(s) with lukewarm, gently flowing water for at least 30 minutes while holding the eyelids open. Neutral saline solution may be used as soon as it is available. If necessary, continue flushing during transport to emergency care facility. Take care not to rinse contaminated water into the unaffected eye or onto face. Quickly transport victim to an emergency care facility. Skin Contact:
If skin contact with contents of an open battery occurs, as quickly as possible remove contaminated clothing, shoes and leather goods. Immediately flush with lukewarm, gently flowing water for at least 30 minutes. If irritation or pain persists, seek medical attention. Completely decontaminate clothing, shoes and leather goods before reuse or discard. Ingestion:
If ingestion of contents of an open battery occurs, NEVER give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 60 to 240 mL (2-8 oz.) of water. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Have victim rinse mouth with water again. Quickly transport victim to an emergency care facility.
Section 5:
Fire Fighting Measures

Flammable Properties:
In the event that this battery has been ruptured, the electrolyte solution contain within the battery would be flammable. Like any sealed container, battery cells may rupture when exposed to excessive heat; this could result in the release of flammable or corrosive materials. Suitable extinguishing Media:
Use water or other extinguishing media appropriate for the surrounding fire.
Unsuitable extinguishing Media:


Explosion Data:

Sensitivity to Mechanical Impact: This may result in rupture in extreme cases.
Sensitivity to Static Discharge: Not applicable
Specific Hazards arising from the
Fires involving lithium batteries can be controlled with water. When water is used, however, Chemical:
hydrogen gas may evolve. In a confined space, hydrogen gas can form an explosive mixture. In this situation, smothering agents are recommended to extinguish the fire. Protective Equipment and
As for any fire, evacuate the area and fight the fire from a safe distance. Wear a pressure- precautions for firefighters:
demand, self-contained breathing apparatus and full protective gear. Fight fire from a protected location or a safe distance. Health: 0
Flammability: 0
Instability: 0
Product Name: High Power Lithium Ion Cell, Phosphate-Based MATERIAL SAFETY DATA SHEET
Section 6:
Accidental Release Measures

Personal Precautions:
Restrict access to area until completion of clean-up. Do not touch the spilled material. Wear adequate personal protective equipment as indicated in Section 8. Environmental Precautions: Prevent material from contaminating soil and from entering sewers or waterways.
Methods for Containment:
Stop the leak if safe to do so. Contain the spilled liquid with dry sand or earth. Clean up spills Methods for Clean-up:
Absorb spilled material with an inert absorbent (dry sand or earth). Scoop contaminated absorbent into an acceptable waste container. Collect all contaminated absorbent and dispose of according to directions in Section 13. Scrub the area with detergent and water; collect all contaminated wash water for proper disposal.
Section 7:
Handling and Storage

Handling
Do not open, dissemble, crush or burn battery. Do not expose battery to extreme heat or fire. Storage:
Store battery in a dry location. Keep at room temperature. Elevated temperatures can result in shortened battery life. Keep out of reach of children.
Section 8:
Exposure Controls and Personal Protection

Engineering Controls:

Use local exhaust ventilation or other engineering controls to control sources of dust, mist, fume and Personal Protection:
Respiratory Protection: Not necessary under normal conditions.
Skin Protection: Not necessary under normal conditions. Wear neoprene or natural rubber gloves if handling an open
Eye Protection: Not necessary under normal conditions. Wear safety glasses if handling an open or leaking battery.
Other Protective
Have a safety shower and eye-wash fountain readily available in the immediate work area. Equipment:

Hygiene Measures:

Do not eat, drink or smoke in work areas. Maintain good housekeeping. Product Name: High Power Lithium Ion Cell, Phosphate-Based MATERIAL SAFETY DATA SHEET

Section 9:
Physical and Chemical Properties
Physical State:
Vapor Pressure:
(mm Hg @ 20°C)

Appearance:
Vapor Density:
Solubility in Water:
Relative Density:
Water / Oil distribution
(water = 1)
coefficient:
Boiling Point:
Odor Type:
Melting Point:
Odor Threshold:
Viscosity:
Evaporation Rate:
(n-Butyl Acetate = 1)

Oxidizing Properties:
Auto Ignition Temperature
Flash Point and Method (°C): Not applicable
Flammability Limits (%):

Section 10: Stability and Reactivity

Stability:

Conditions to Avoid:
Avoid exposing the battery to fire or high temperature. Do not disassemble, crush, short or install with incorrect polarity. Avoid mechanical or electrical abuse. Incompatible Materials:

Hazardous Decomposition

This material may release toxic fumes if burned or exposed to fire. Products:

Possibility of Hazardous
Reactions:

Product Name: High Power Lithium Ion Cell, Phosphate-Based MATERIAL SAFETY DATA SHEET

Section 11: Toxicological Information

Irritation:
Risk of irritation occurs only if the cell is mechanically, thermally or electrically abused to the point of compromising the enclosure. If this occurs, irritation to the skin, eyes and respiratory tract may occur. Sensitization:

Neurological Effects:


Teratogenicity:


Reproductive Toxicity:

Mutagenicity (Genetic Effects): Not applicable
Toxicologically Synergistic
Materials:

Section 12: Ecological Information

Ecotoxicity:
Mobility:

Persistence and degradability:


Bioaccumulative potential:


Other adverse effects:


Section 13: Disposal Considerations

Waste Disposal Method:
Battery recycling is encouraged. Do NOT dump into any sewers, on the ground or into any body of water. Store material for disposal as indicated in Section 7 Handling and Storage. Dispose of in accordance with local, state and federal laws and regulations. Dispose of in accordance with local, provincial and federal laws and regulations. Waste must be disposed of in accordance with relevant EC Directives and national, regional and local environmental control regulations. For disposal within the EC, the appropriate code according to the European Waste Catalogue (EWC) should be used.
Section 14: Transport Information:

Lithium-ion batteries comply with all applicable shipping regulations as prescribed by industry and legal standards which includes
compliance with the UN Recommendations on the Transport of Dangerous Goods; IATA Dangerous Goods Regulations Special
Provision A45, and applicable U.S. DOT regulations for the safe transport of Lithium-ion batteries. Each cell or battery has been
tested under provisions of the UN Manual of Tests and Criteria, Part III, sub-section 38.3 and are classified as non-dangerous goods.
Product Name: High Power Lithium Ion Cell, Phosphate-Based MATERIAL SAFETY DATA SHEET

Section 15: Regulatory Information
USA

TSCA Status: All ingredients in the product are listed on the TSCA inventory.
SARA Title III:
California Prop 65 : This product does not contain chemicals known to the State of California to cause cancer or
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS Classification: Not Controlled
New Substance Lithium hexafluorophosphate is listed on the NDSL. All other ingredients in the product are listed,
Notification as required, on Canada’s Domestic Substances List (DSL).
Regulations:
NPRI Substances This product does not contain any NPRI chemicals.
(National Pollutant
Release Inventory):
EC Classification for the
Substance/Preparation:
Symbol: This product is not classified as dangerous according to Directive 1999/45/EC and its amendments.
Risk Phrases: None
Safety Phrases: S2: Keep out of the reach of children.
Section 16: Other Information

Preparation Information:
Preparation Date:


Revision Date:


Revision Summary:

November 2, 2006: Added new product code, Section 1. March 27, 2007: Added new product codes, Section 1. Prepared by:
704 Mara Street, Suite 210, Pt. Edward, ON N7V 1X4 www.lehder.com
Disclaimer:

While LEHDER Environmental Services Limited believes that the data set forth herein is accurate, as of the date hereof, LEHDER makes no warranty with respect thereto and expressly disclaims all liability for reliance thereon. Such data is offered solely for your consideration, investigation and verification. Manufacturer Disclaimer:
The information and recommendations set forth are made in good faith and believed to be accurate at the date of preparation. A123 Systems makes no warranty expressed or implied with respect to this information and recommendations and disclaims all liability from reliance on it.

Source: http://fmp.unl.edu/msds/A123%20Lithium%20Ion%20Cell.pdf

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