MSDS#: KIP112900-PC4 Material Safety Data Sheet POLYMER CLEAR Page 1 of 1 Section 1 - Identification of the Substance/Preparation and of the Company/Undertaking POLYMER CLEAR Chemical
Family: ACRYLIC POLYMER Product Use: NAIL POLYMER Emergency Phone Numbers: (800) 535 - 5053 Product #: various
Section 2 - Composition/Information on Ingredients Section 2 - Composition/Information on Ingredients Chemical Identity CAS Numbers INCI Name Exposure Carcinogen OSHA ACGIH Hazard Symbols: Xi Risk Phrases: R36/37/38 Safety Phrases: S18, S22, S24/25, S38 This product is not considered hazardous by OSHA Hazard Communication Standard. Section Identification EMERGENCY OVERVIEW
This information is based on findings from related or similar materials.
• Dust may cause irritation of the nose, throat, and lungs.
• This product may contain particulate, not otherwise classified (Nuisance Dust)
Potential Health Effects, Signs and Symptoms of Exposure: Primary Route of Entry
Eyes or skin (No absorption); inhalation of dust.
Higher concentration can irritate eyes. May cause eye irritation or damage.
Repeated or prolonged exposure may cause allergic skin rashes.
Higher concentration can irritate respiratory system.
Possible temporary discomfort due to inhalation of dust concentration above the permissible exposure limit. Dust may cause irritation of the nose, throat, and lungs.
For Polymer: OSHA classifies this material as Particulates, Not Otherwise Classified. Eyes, skin and Respiratory tract may be irritated by gross overexposure to Particulates, Not Otherwise Classified, no matter how they are generated. Avoid inhalation of dust. Keep dust out of eyes to prevent possible irritation. For decomposition product: Methyl Methacrylate Monomer; Liquid or high vapor concentration can irritate eyes, respiratory system and cause skin rashes. Prolonged exposure can lead to headaches, nausea, staggering gait, confusion, drowsiness and unconsciousness. Repeated and prolonged over exposure may cause permanent brain and nervous system damage, allergic skin rashes, eye corrosion and permanent injury, as well as changes in liver and kidney function or damage. For Benzoyl Peroxide: repeated or prolonged contact may cause skin sensitization.
NOTE: Refer to Section 11, Toxicological Information for Details Section Measures
Flush with water for 15 minutes, including under eyelids. Get medical help if discomfort persists.
Wash with soap and water. Get medical help if discomfort persists.
Revised Date: 10/29/2004 | Replaces Date: 10/12/2004 MSDS#: KIP112900-PC4 Material Safety Data Sheet POLYMER CLEAR Page 2 of 2
Remove to fresh air. Get medical help if discomfort persists.
Rinse mouth out with water. Call doctor if amount was large.
Fighting Measures Flash Point(°F/°C) Flammable Limit(vol%) Auto-ignition Temperature(vol%)
Avoid extinguishing methods that generate dust clouds. Water streams can disperse dust into
air, producing a fire hazard and possible explosion hazard. Fire-fighters should wear self -contained breathing apparatus.
Polymer dust is combustible, explosive limits of the polymer particles suspended in air are approximately those of coal dust.
Accidental Measures
Sweep up to avoid slipping hazard. Keep airborne particulates at a minimum when cleaning
Handling
Observe precautions found on the label. Wash face and hands thoroughly with soap and water after handling and before eating, drinking or smoking.Avoid prolonged or repeated contact with skin. Avoid contamination. Use only with adequate ventilation.
Store in cool, dry place away from heat, sparks, flame and direct sunlight. Close container after each use. Ground all metal conrainers when transferring. Use explosion-proof equipment Store away from combustibles and incompatible materials.
Polymer dust is combustible, explosive limits of the polymer particles suspended in air are approximately those of coal dust.
Section 8 - Exposure Controls / Personal Protective Equipment
Use good local exhaust at processing equipment, including buffers, sanders, grinders and polishers. High temperature processing equipment should be well ventilated. Use explosion-proof equipment.Provide ventilation if necessary to control exposure levels below airborne exposure limits.
Personal Protective Equipment
Dust collectors are recommended for handling powder in bulk.
Use safety glasses and have eye flushing equipment immediately available.
Minimize contamination by following good industrial practice. Wearing nitrile, neoprene, pvc, latex ot other impermeable gloves is recommended.
Avoid breathing dust and mist. Use dust mask.
Section 9 - Physical and Chemical Properties Appearance Odor Odor Threshold Specific Gravity Viscosity % Volatile Boiling Point/ Decomposition Octanol/Water Vapor Vapor Evaporation Ignition Solubility Freezing Point Temperature Partitioning Coefficient Pressure: Density Flash Point(°F/°C) Flammable Limit(vol%) Auto-ignition Temperature(vol%) Stability Reactivity Stability: Stable Incompatibility (Materials to Avoid): Strong
Revised Date: 10/29/2004 | Replaces Date: 10/12/2004 MSDS#: KIP112900-PC4 Material Safety Data Sheet POLYMER CLEAR Page 3 of 3 Hazardous Decomposition Products: methacrylate monomers Conditions to Avoid: Heating above 240 deg C , 464 deg F Hazardous Polymerization: will not occur Toxicological Information Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Toxicity Irritation - skin Irritation - Eye
Since this product contains a very low concentration of active components, the primary toxicological information is derived from the copolymers. Further hazardous properties cannot be excluded. The product should be handled with care when dealing with chemicals.
Sensitization Mutagenicity Sub-chronic Toxicity Ecological Information Ecotoxicological Information Acute Toxicity Acute Toxicity Acute Toxicity Bioconcentratio Toxicity to to Invertebrates Sewage Bacteria
Flathead minnows and goldfish TLm24 : 420 ppm
Chemical Fate Information Biodegradability Chemical Oxygen Demand
To the best of our knowledge, the ecotoxocological and chemical fate properties have not been thoroughly investigated. Do not allow to enter drinking water supplies, wastewater, or soil.
Disposable Considerations
May be disposed of in a landfill or incinerated. Follow Federal, State and Local regulations for disposal. For EU Member States, please refer to any relevant Community provisions relating to waste. In their absence, it is useful to remind the user that national or regional provisions may be in force.
Transport Information DOT (49 CFR 172) Emergency Response Guidebook (ERG) #: IATA (DGR): Emergency Response Guidance (ICAO)#: IMO (IMDG):
Special Provisions & Stowage/Segregation:
Emergency Schedule (EmS)#: Other Information: Flash point > 100ºC Regulatory Information US Federal Regulations
This product contains the following hazardous air pollutants (HAP's) or ozone dipleting substances (ODS's), as defined by the U. S. Clean Air Act:
This product contains the following chemicals listed under the U.S. Clean Water Act Priority Pollutant List:
Revised Date: 10/29/2004 | Replaces Date: 10/12/2004 MSDS#: KIP112900-PC4 Material Safety Data Sheet POLYMER CLEAR Page 4 of 4
This product has not been cleared by the FDA for use in food packaging and/ or other applications as an indirect food additive.
This product is not considered a hazardous chemical under the OSHA Hazard Communication Standard.
This product contains no chemicals considered to be hazardous waste under RCRA ( 40 CFR 261).
This product contains no chemicals regulated under Sec. 302 as extremely hazardous substances.
This product contains no chemicals regulated under Sec. 304 as extremely hazardous chemicals for emergency release notification ( "CERCLA " List).
This product does not contain hazardous substances under the OSHA Hazard Communication Standard, and is not regulated under Section 311-312 (40 CFR 370).
This product contains the following chemicals outlined in SARA Title III: Section 313:
This product contains chemicals listed on the TSCA inventory or otherwise complies
with TSCA premanufacture notification requirements.
None of the chemicals listed have a SNUR under TSCA.
State Regulations International Regulations
Polymethyl methacrylate CAS# 9011-14-7 is on the DSL List. WHMIS = n/da
Polyethylmethacrylate CAS# 9003-42-3 is on the DSL List. WHMIS = n/da Benzoyl Peroxide CAS #94-36-0 is on the DSL list. WHMIS = C, D2B, B4
Polymer Clear:
• HAZARD SYMBOLS: Xi: Irritant • RISK PHRASES: R36/37/38: Irritating to eyes, respiratory system and skin • SAFETY PHRASES: S18:Handle and open container with care,S22:do not breath dust,S24/25:avoid contact with skin and eyes,S38:in case of insufficient ventilation, wear suitable respiratory equipment. Information Hazard Rating System (Pictograms) NFPA: HMIS: 1 Flammability Reactivity
* - Respiratory protection may be necessary depending on conditions of use. Refer to Section VIII of this MSDS for respiratory protection guidelines. OSHA PEL for nuisance dust: 15 mg/m3 (total dust) 5 mg/m3 (respirable dust) ACGIH PEL for nuisance dust: 10 mg/m3
Section 2 % changed from <,> to range, headers changed, format update
The information presented herein was obtained from sources considered to be reliable. However, this information is provided without any warranty, expressed or implied, regarding its correctness or suitability for consumers intended use and/or application. For this and other reasons, we assume no responsibility and expressly disclaim liability for loss, damage or expense arising out of any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared expressly for this product. Use the materials only as directed. If the product is used as a
Revised Date: 10/29/2004 | Replaces Date: 10/12/2004 MSDS#: KIP112900-PC4 Material Safety Data Sheet POLYMER CLEAR Page 5 of 5 component of another product, the information contained within the MSDS may not be applicable. If one could have any concerns with or problems understanding this MSDS form, please direct all questions to INFOTRAC, Chemical Emergency Resources System at 1(800) 535-5053.
Revised Date: 10/29/2004 | Replaces Date: 10/12/2004
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MSDS#: KIP112900-PC4