Chemwatch msds 5107-45

PERMATEX BEARING MOUNT FOR RELAXED FITS 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 6-Feb-2007
CHEMWATCH 5107-45
CC317ECP
Version No:4
CD 2007/1 Page 1 of 7
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
PERMATEX BEARING MOUNT FOR RELAXED FITS 250ML
SYNONYMS
"Product Code: 68025", "anaerobic adhesive"
PRODUCT USE
Anaerobic bearing mount adhesive for repairing worn machinery parts.
SUPPLIER
Company: Australian Timken
Address:
5 Daveyduke Road
Ballarat
VIC, 3350
AUS
Telephone: +61 3 5320 2700
Fax: +61 3 5338 1186
HAZARD RATINGS
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
May cause SENSITISATION by skin contact.
Harmful: danger of serious damage to health by prolongedexposure through inhalation and if swallowed.
Harmful to aquatic organisms, may cause long- term adverseeffects in the aquatic environment.
HARMFUL- May cause lung damage if swallowed.
Keep container in a well ventilated place.
Avoid exposure - obtain special instructions before use.
To clean the floor and all objects contaminated by thismaterial, use water and detergent.
Take off immediately all contaminated clothing.
In case of accident or if you feel unwell IMMEDIATELYcontact Doctor or Poisons Information Centre (show label ifpossible).
continued.
PERMATEX BEARING MOUNT FOR RELAXED FITS 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 6-Feb-2007
CHEMWATCH 5107-45
CC317ECP
Version No:4
CD 2007/1 Page 2 of 7
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
2, 2- bis[4- (2- methacryloxy)ethoxy)phenyl]propane bisphenol A/ propylene oxide/ fumarate copolymer Section 4 - FIRST AID MEASURES
SWALLOWED
- For advice, contact a Poisons Information Centre or a doctor at once.
- Urgent hospital treatment is likely to be needed.
If this product comes in contact with the eyes:
- Immediately hold eyelids apart and flush the eye continuously with running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting
the upper and lower lids.
If skin or hair contact occurs:
- Immediately flush body and clothes with large amounts of water, using safety shower if available.
- Quickly remove all contaminated clothing, including footwear.
- If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
NOTES TO PHYSICIAN
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
- Foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.
- Water spray or fog - Large fires only.
FIRE FIGHTING
- Alert Fire Brigade and tell them location and nature of hazard.
- Wear full body protective clothing with breathing apparatus.
- Prevent, by any means available, spillage from entering drains or water course.
- Use water delivered as a fine spray to control fire and cool adjacent area.
- Avoid spraying water onto liquid pools.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
FIRE/EXPLOSION HAZARD
- Combustible.
- Slight fire hazard when exposed to heat or flame.
- Heating may cause expansion or decomposition leading to violent rupture of containers.
- On combustion, may emit toxic fumes of carbon monoxide (CO).
- May emit acrid smoke.
- Mists containing combustible materials may be explosive.
Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may
result.
HAZCHEM: None
Personal Protective Equipment
Breathing apparatus.
Gas tight chemical resistant suit.
Limit exposure duration to 1 BA set 30 mins.
continued.
PERMATEX BEARING MOUNT FOR RELAXED FITS 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 6-Feb-2007
CHEMWATCH 5107-45
CC317ECP
Version No:4
CD 2007/1 Page 3 of 7
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Avoid breathing vapours and contact with skin and eyes.
Control personal contact by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
No smoking, naked lights or ignition sources.
Contain spill with sand, earth or vermiculite.
Collect recoverable product into labelled containers for recycling.
Absorb remaining product with sand, earth or vermiculite.
Collect solid residues and seal in labelled drums for disposal.
Wash area and prevent runoff into drains.
If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
DO NOT allow clothing wet with material to stay in contact with skin.
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- Prevent concentration in hollows and sumps.
- DO NOT enter confined spaces until atmosphere has been checked.
- Avoid smoking, naked lights or ignition sources.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.
SUITABLE CONTAINER
- Metal can or drum
- Packaging as recommended by manufacturer.
- Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Exposure to light, free radical initiators, iron, rust, oxidisers, and strong bases.Storage beyond expiration date, may initiate
polymerisation.
Contamination with polymerisation catalysts - peroxides, persulfates, oxidising agents - also strong acids, strong alkalies, will
cause polymerisation with exotherm - generation of heat.
Polymerisation of large quantities may be violent - even explosive.
STORAGE REQUIREMENTS
WARNING: Decomposition may occur after prolonged storage.
Rotate all stock to prevent ageing. Use on FIFO (First In-First Out) basis.
- Store in original containers.
- Keep containers securely sealed.
- No smoking, naked lights or ignition sources.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
continued.
PERMATEX BEARING MOUNT FOR RELAXED FITS 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 6-Feb-2007
CHEMWATCH 5107-45
CC317ECP
Version No:4
CD 2007/1 Page 4 of 7
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source
Material
_________________
__________________
Australia Exposure
bisphenol A/
Standards
propylene oxide/
fumarate copolymer
(Inspirable dust
(Not specified))
Australia Exposure
saccharin
Standards
(Inspirable dust
(Not specified))
The following materials had no OELs on our records
• 2,2-bis[4-(2-methacryloxy)ethoxy)phenyl]propane:
CAS:24448-20-2
• 2-hydroxypropyl methacrylate:
CAS:923-26-2
CAS:27813-02-1
• cumyl hydroperoxide:
CAS:80-15-9
PERSONAL PROTECTION
RESPIRATOR
- Chemical goggles.
- Full face shield may be required for supplementary but never for primary protection of eyes- Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a reviewof lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aidpersonnel should be trained in their removal and suitable equipment should be readily available. In the event of chemicalexposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the firstsigns of eye redness or irritation - lens should be removed in a clean environment only after workers have washed handsthoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.
NOTE: The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and otherprotective equipment, to avoid all possible skin contact.
- Overalls.
- P.V.C. apron.
- Barrier cream.
- Skin cleansing cream.
- Eye wash unit.
ENGINEERING CONTROLS
Local exhaust ventilation usually required. If risk of overexposure exists, wear approved respirator. Correct fit is essential toobtain adequate protection. Supplied-air type respirator may be required in special circumstances. Correct fit is essential toensure adequate protection.
An approved self contained breathing apparatus (SCBA) may be required in some situations.
Provide adequate ventilation in warehouse or closed storage area.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Green liquid with a sharp odour; partially miscible with water.
PHYSICAL PROPERTIES
Liquid.
Solubility in water (g/L): Partly Miscible continued.
PERMATEX BEARING MOUNT FOR RELAXED FITS 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 6-Feb-2007
CHEMWATCH 5107-45
CC317ECP
Version No:4
CD 2007/1 Page 5 of 7
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
May cause SENSITISATION by skin contact.
Harmful: danger of serious damage to health HARMFUL- May cause lung damage if swallowed.
Vapours may cause dizziness or suffocation.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
2,2-BIS[4-(2-METHACRYLOXY)ETHOXY)PHENYL]PROPANE:No significant acute toxicological data identified in literature search.
Based on the available oncogenicity data and without a better understanding of the carcinogenic mechanism the Health andEnvironmental Review Division (HERD), Office of Toxic Substances (OTS), of the US EPA previously concluded that all chemicalsthat contain the acrylate or methacrylate moiety (CH2=CHCOO or CH2=C(CH3)COO) should be considered to be a carcinogenic hazardunless shown otherwise by adequate testing.
This position has now been revised and acrylates and methacrylates are no longer de facto carcinogens.
2-HYDROXYPROPYL METHACRYLATE:for CAS 963-26-2 2-hydroxypropyl methacrylateOral (mouse) LD50: 7964 mg/kgOral (rat) LD50: 5050 mg/kg * NOTE: Allergic contact dermatitis is reported following exposure ofguinea pigs (mild) and humans (severe).
for CAS 27813-02-1 1-hydroxypropyl methacrylateOral (rat) LD50: 11,200 mg/kgBased on the available oncogenicity data and without a better understanding of the carcinogenic mechanism the Health andEnvironmental Review Division (HERD), Office of Toxic Substances (OTS), of the US EPA previously concluded that all chemicalsthat contain the acrylate or methacrylate moiety (CH2=CHCOO or CH2=C(CH3)COO) should be considered to be a carcinogenic hazardunless shown otherwise by adequate testing.
This position has now been revised and acrylates and methacrylates are no longer de facto carcinogens.
BISPHENOL A/ PROPYLENE OXIDE/ FUMARATE COPOLYMER:TOXICITY Skin (rabbit): non- irritating[ICI America] Oral (rat) LD50: 382 mg/kgSkin (rabbit): 500 mg - MildEye (rabbit): 1 mgBacterial cell mutagenEquivocal tumorigen by RTECS criteria Oral (mouse) LD50: 17000 mg/kgThe substance is classified by IARC as Group 3: NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
MATERIAL
CARCINOGEN
REPROTOXIN
SENSITISER
________________________
____________________
________________
________________
________________
saccharin
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: saccharin Category: 3
continued.
PERMATEX BEARING MOUNT FOR RELAXED FITS 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 6-Feb-2007
CHEMWATCH 5107-45
CC317ECP
Version No:4
CD 2007/1 Page 6 of 7
Section 12 - ECOLOGICAL INFORMATION
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Section 13 - DISPOSAL CONSIDERATIONS
- Containers may still present a chemical hazard/ danger when empty.
- Return to supplier for reuse/ recycling if possible.
Otherwise:
- If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to
store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
- Where possible retain label warnings and MSDS and observe all notices pertaining to the product.
Section 14 - TRANSPORTATION INFORMATION
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: S5
REGULATIONS
2,2-bis[4-(2-methacryloxy)ethoxy)phenyl]propane (CAS: 24448-20-2) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
2-hydroxypropyl methacrylate (CAS: 923-26-2) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
2-hydroxypropyl methacrylate (CAS: 27813-02-1) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
bisphenol A/ propylene oxide/ fumarate copolymer (CAS: 39382-25-7) is found on the following regulatory lists;
Australia Exposure Standards
Australia Inventory of Chemical Substances (AICS)
Australia Poisons Schedule
cumyl hydroperoxide (CAS: 80-15-9) is found on the following regulatory lists;
Australia Dangerous Goods Code Draft 7th Edition - Goods too Dangerous to be Transported
Australia Dangerous Goods Code Draft 7th Edition - Organic Peroxides
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
saccharin (CAS: 81-07-2) is found on the following regulatory lists;
Australia - Australia New Zealand Food Standards Code - Food Additives - Schedule 1 Permitted uses of food additives by food
Australia Exposure Standards
Australia Inventory of Chemical Substances (AICS)
International Agency for Research on Cancer (IARC) Carcinogens
Section 16 - OTHER INFORMATION
Denmark Advisory list for selfclassification of dangerous substances
Substance
Suggested codes
2, 2- bis[4- (2-
24448- 20-
N; R50/53
methacryloxy)ethoxy)phenyl]propane
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name
continued.
PERMATEX BEARING MOUNT FOR RELAXED FITS 250ML
Chemwatch Material Safety Data Sheet
Issue Date: 6-Feb-2007
CHEMWATCH 5107-45
CC317ECP
Version No:4
CD 2007/1 Page 7 of 7
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act,no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700. Issue Date: 6-Feb-2007
Print Date: 7-Feb-2007

Source: http://www.permatex.com.au/MSDS/68025.pdf